Precise Design of Nitrogen-containing Heterocyclic Copolymers Study of their Self-assembly Behavior for the Application of Heavy Metals Adsorption Sensing

  • Publication Date: 2020-04-03
Application Dept. Dept. of Chemical Engineering
Principal Investigator Prof. Chih-Feng Huang ( Personal Webpage )
Project Title Precise Design of Nitrogen-containing Heterocyclic Copolymers and Study of their Self-assembly Behavior for the Application of Heavy Metals Adsorption and Sensing
Co-Principal Investigator 1. Asst. Prof. Han-Yu Hsueh, Dept. of Materials Science & Engineering 2. A.P. Yu-Ting Liu, Dept. of Soil & Environmental Sciences
Co-Investigator
Abstract Linear or star block copolymers (BCPs) generally have incompatible segments because of their different physical and chemical property. But due to the covalent bonds between the segments, BCPs perform micro-scale and orderly microphase separation in the bulk, thin film, and solution states. This process is so-called self-assembly and attain microphase separations which provide a variety of applications. Star-like polymers have recently been a novel research topic and applications. In this project, we focus in a special material of [polystyrene-block-poly(2-vinylpyridine)]4 ([PS-b-P2VP]4) 4-arm star-shaped BCPs. We will use TEM, SAXS, AFM, DLS, and other instruments to observe their self-assembly behaviors. After processing the BCPs, it will be investigated the adsorption behaviors of heavy metals (Au, Ag, Pd, Pt, Cr) in different conditions (e.g., temperature, pressure, pH).