以活性聚合法精準設計含氮雜環之共聚物與其自組裝研究並應用於重金屬吸附與偵測

  • 刊登日期: 2020-04-06
申請系所(單位) 化學工程學系
計畫主持人 黄智峯 教授 ( 個人網頁 )
計畫名稱(中文) 以活性聚合法精準設計含氮雜環之共聚物與其自組裝研究並應用於重金屬吸附與偵測
計畫名稱(英文) Precise Design of Nitrogen-containing Heterocyclic Copolymers and Study of their Self-assembly Behavior for the Application of Heavy Metals Adsorption and Sensing
共同主持人 1. 薛涵宇 助理教授 / 材料系 2. 劉雨庭 副教授 / 土壤環境工程學系
協同主持人
中文摘要 線性(Linear)或星狀(Star)嵌段共聚物(Block copolymers)因其鏈段間的物性及化性不同而互不相容,但由於鏈段間存有共價鍵,其於塊材(Bulk)、薄膜(Thin film)與溶液(Solution)態下,會使不相容鏈段發生微觀尺度且有序的相分離,此過程稱為自組裝(Self-assembly),這些微相分離(Microphase separation)有著廣泛的應用性,而星狀高分子更是近來在合成與應用上的新穎的研究方向。本研究利用活性聚合合成多樣構形的[Polystyrene-block-Poly(2-vinylpyridine)]4 ([PS-b-P2VP]4)四臂星狀嵌段共聚物,利用TEM、SAXS、AFM、DLS等儀器,觀察其自組裝行為。將此類材料加工後,將研究不同條件下(溫度、壓力、酸鹼值),應用於重金屬(Au、Ag、Pd、Pt、Cr)之吸附行為。
英文摘要 Linear or star block copolymers (BCPs) generally have incompatible segments because of their different physical and chemical property. But due to the covalent bonds between the segments, BCPs perform micro-scale and orderly microphase separation in the bulk, thin film, and solution states. This process is so-called self-assembly and attain microphase separations which provide a variety of applications. Star-like polymers have recently been a novel research topic and applications. In this project, we focus in a special material of [polystyrene-block-poly(2-vinylpyridine)]4 ([PS-b-P2VP]4) 4-arm star-shaped BCPs. We will use TEM, SAXS, AFM, DLS, and other instruments to observe their self-assembly behaviors. After processing the BCPs, it will be investigated the adsorption behaviors of heavy metals (Au, Ag, Pd, Pt, Cr) in different conditions (e.g., temperature, pressure, pH).